Designing, fabricating, andor maintaining carbon steel equipment and piping that is exposed to caustic environments. As a general rule, the resistance to caustic solutions increases with. The duplex steel exhibited the best performances while the n08904 steel had the worst scc resistance. Effect of alloy structure, hydroxide concentration, and. Caustic is found to be a primary cause of stresscorrosion cracking. This is a type of deterioration which can be linked to corrosion and corrosion control processes. Avoiding caustic stress corrosion cracking of carbon steel refinery equipment fontsize. Standard recommended practice avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping. The most common material of construction in caustic environments is carbon steel. Stress corrosion cracking of duplex stainless steels in. Caustic stress corrosion cracking of mild steel springerlink. Standard practice avoiding caustic stress corrosion cracking. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel.
Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Mild steels steels with low carbon and low alloy content and stainless steels will. Nace standard sp04032015 avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping. Other terms for caustic scc used in past literature include caustic embrittlement, caustic cracking, and alkaline cracking. This standard incorporates the findings of that survey as they apply to refinery applications. Avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Stress corrosion cracking of type 316 stainless steel in. Sp04032015, avoiding caustic stress corrosion cracking. Caustic is found to be a primary cause of stress corrosion cracking. Introduction caustic stress corrosion cracking scc may be of potential interest for many industrial fields.
Avoiding caustic stress corrosion cracking of refinery equipment and piping. The lmec and general electric ge ran a series of tests to evaluate the effect of heating rate on caustic stress corrosion cracking scc for alloys either used or considered for the lltr. Oct 15, 2017 caustic corrosion is a type of corrosion that occurs in metal equipment e. A summary of the temperatures and caustic concentration ranges that can result in caustic scc for carbon steel and type304 stainless steel is given. This standard practice establishes guidelines to avoid caustic scc of equipment and piping. Caustic stress corrosion cracking inspectioneering. The material performance in these environments is governed by the stability of the passive surface film, which develops as a function of alloy microstructure, chemical composition, and associated environmental. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. It was later known as stress corrosion cracking which is in turn replaced by caustic cracking.
In many ways, caustic scc of stainless steel represents a forgotten phenomenon, since it was researched, studied and quantified in the 60s and 70s. Aug 09, 2015 nace sp0403 latest revision, avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping houston, tx. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620 o c to 705 o c, depending upon prior solution treating temperature. In many ways, caustic scc of stainless steel represents a forgotten phenomenon, since it was researched, studied and quantified in. Important differences are discussed between striationbased e. Stress corrosion cracking behavior of nickel base alloys. Compressive residual stress generated by bristle blasting. Stress corrosion cracking of 304l stainless steel in sodium. High concentration caustic solutions are known to cause stress corrosion cracking in carbon steel at elevated temperature. Caustic service material selection corrosion engineering. Scc kinetics were studied under freely corroding potentials e corr.
Discussion caustic stress corrosion cracking of steels is one of the oldest known forms of scc, dating back to the days of the early steam locomotives, when it was responsible for countless explosions of riveted boilers trethewey et al. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. The required tensile stresses may be in the form of directly applied stresses or in the form of residual.
Natural conditions for caustic cracking of a mild steel. The results of this study are combined with other information on amounts of elements and anions in deposits and on steam. There is caustic stress corrosion cracking when carbon steel is exposed to concentrated caustic solution. Caustic scc is driven by tensile stress, susceptible material and concentration of caustic. Stainless steels are more resistant to general corrosion compared with carbon steel. Stress corrosion cracking the international institute of. Alloy 400 n04400 and alloy 600 n06600 also have excellent stress corrosion resistance. However, when sulfides are present in caustic solutions the scc of austenitic stainless steels has been reported to occur at lower temperatures. Since stress can be present in these components, as generated by fabrication, structural loads, deformation in service, and possible wedging action by corrosion products, conditions are potentially available for the mechanism of caustic stress corrosion cracking cscc. As with other forms of stress corrosion cracking, caustic cracking will. Caustic cracking caustic embrittlement stress corrosion cracking scc hydrogeninduced cracking hic hydrogen blistering. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping this standard practice establishes guidelines to avoid caustic scc of cs refinery equipment and piping. Nace standard sp04032015 avoiding caustic stress corrosion.
Corrosion behaviour of type 316l stainless steel in hot. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Higher naoh concentrations and exposure temperatures resulted in a reduced stability of the electrochemical passivity domain. Effect of heating rate on caustic stress corrosion cracking. Stress corrosion cracking of stainless steels in high temperature.
Rp04032003 avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping. Singh 1 school of materials science and engineering, georgia institute of technology, 500 10th st. Industrial experience on the caustic cracking of stainless steels. Caustic embrittlement was first used to describe the cracking of riveted mild steel boiler plates due to local deposition of concentrated hydroxide at temperatures of 200 to 250 o c 400 to 480 o f. So, lack of pwht will increase susceptibility, mostly. Pdf a case study on caustic corrosion in refinery piping. This standard recommended practice is intended to provide guidance to those designing, fabricating, andor maintaining carbon steel equipment and piping that is exposed to caustic environments. This paper discusses a study of the role of sulfide in caustic solutions on scc of austenitic stainless at t50c. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620oc to 705oc, depending upon prior solution treating. Abstract caustic stress corrosion cracking scc experiments have been conducted on type 304, 304l, 316, 316l, and uss 18182 stainless steels. It provides an introduction to stress corrosion cracking for those who are unfa.
Nace sp04032015 avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping. Stress corrosion cracking of type 304l stainless steel in. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. Caustic corrosion is a type of corrosion that occurs in metal equipment e. Despite the extensive qualification of inconel for specific applications, a number of corrosion problems have arisen with inconel tubing. The useful safe limit of carbon steel is approximately 150 o f65 o c, both with regard to caustic stress corrosion cracking cscc and corrosion. When sulfides are present in caustic solutions the scc has been reported to occur at lower temperatures. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. This standard establishes recommended practices to avoid caustic scc of cs refinery equipment and piping. Mechanisms of stresscorrosion cracking asm international. Standard practice avoiding caustic stress corrosion. Failure of carbon steel piping by caustic stress corrosion cracking embrittlement and caustic gouging.
Stress corrosion cracking international institute of. Austenitic stainless steels are known to be susceptible to caustic stress corrosion cracking scc above approximately 121c. Stress corrosion cracking of type 304l stainless steel in sodium sulfidecontaining caustic solutions p. This calculation establishes the conditions where heat of dilution will not cause the solution temperatureconcentration to exceed the boundary for stress corrosion cracking as established by nace international. This form of corrosion is controlled by maintaining low chloride ion and oxygen content in the environment and use of low carbon steels. Sp04032015, avoiding caustic stress corrosion cracking of. Stress corrosion cracking of stainless steel components in. Stress corrosion cracking of stainless steels in high. Sp04032015, avoiding caustic stress corrosion cracking of refinery equipment and piping available for download designing, fabricating, andor maintaining carbon steel equipment and piping that is exposed to caustic environments. As a general rule, the resistance to caustic solutions increases with increasing nickel content. Carbon steel in caustic service corrosion engineering.
The environments used were deoxygenated 50% naoh sol. Aug 01, 2018 caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. The stress corrosion cracking scc behavior of cold worked mild steel in hot, aqueous, 33 pct naoh solutions was studied with prefatigue cracked double cantilever beam specimens. However, many dss grades have been reported to undergo corrosion and stress corrosion cracking in some aggressive environments such as chlorides and sulfidecontaining caustic. Exposure to room temperature environment showed parabolic weight loss behaviour, with corrosion rates of up to 0. Its acceptance does not in any respect preclude anyone, whether he or she has adopted the standard or not, from manufacturing. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Nace rp 0775 download solution manual probability and computing standard recommended practice control of external corrosion on underground or submerged metallic piping systems this nace international standard represents.
Nace international standard practice avoiding caustic. Api rp 945 latest revision, avoiding environmental cracking in amine units washington, dc. Nace sp0403 avoiding caustic stress corrosion cracking of. These alloys can however suffer from caustic stress corrosion cracking at caustic concentrations above 70% at temperatures above 290crmo c 550f. The corrosion of stainless steel in hot caustic environment has been the subject of a number of investigations, typically with a focus on kraft pulping liquors 1,2,3,4,5,6,7,8,9,10,11. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Sulfide stress cracking ssc hightemperature hydrogen attack. Specialized corrosion doehdbk1015193 corrosion ch02 rev. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Sp04032008 sp04032008 avoiding caustic stress corrosion. Discussion caustic stress corrosion cracking of steels is one of the oldest known forms of scc, dating back to the days of the early steam locomotives, when it was responsible for countless explosions of riveted boilers trethewey et. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress corrosion cracking of stainless steels in high temperature caustic. The stress corrosion cracking behavior in caustic solutions 200 gl sodium hydroxide, 10 gl sodium chloride of three austenitic 18cr10ni2.
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